MultiTek Measuring the Sulfur Content of Petrol using ASTM D5453

PAC Multitek from John Morris Scientific

Combustion and UV fluorescence have been the favoured method to classify intermediate streams, feedstock and finished hydrocarbon products due to dynamic range, accuracy, linearity  and strength.

Here, we’re concerned with the total sulfur content determination in petrol based on the ASTM D5453 Standard Test Method. As sulfur is a ubiquitous element in hydrocarbon streams and is responsible for a number of undesirable effects such as catalyst poisoning, detrimental product quality and ecosystem pollution, it is important to quantify and monitor its content in every step of the industry’s technical operations.PAC Antek Multitek from John Morris Scientific

Principle of Operation

Sample components combust to form CO2 and H2O when hydrocarbon samples are introduced into a pyrotube at 1050°C. Sulfur compounds are present in hydrocarbon mixtures and fossil fuels in a wide variety of forms and chemical nature, however as described in the general reaction equipment, they also form combustion products as described in the general reaction equation (I).

R – S + O2 → CO2 + SO2 + H2O      (I)

The measurement of sulfur may be altered by water in the liquid phase or vapour phase and the combustion product must have the water removed before entering the reaction chamber where SO2 molecules get excited and relaxed as per equations (II) and (III) below. A PMT set at the right wavelength range will determine the emission signal of the sulfur species.

SO2 + hv (190-230nm) → SO2*      (II)

SO2* → SO2 + hv (230-450nm)      (III)

Reformulated Petrol (RFG) Analysis

Samples were studied in the MultiTek analyzer in a vertical configuration with an autosampler and UV Fluorescence detector.

In order to validate, the MultiTek performance was compared with results from the ASTM Proficiency testing Program (PTP) on Reformulated Petrols.


Using dibenzothiophene (DBT) in toluene, the MultiTek VNS analyzer was calibrated in a range from 0 to 25mg/kg. The instrument parameters used for RFG analysis and calibration are listed in Table 1. Figure 1 shows the sulfur calibration curve. The resulting correlation coefficient was more than 0.9999.

Table 1. Instrument parameters

Calibration method
Inlet Ar flow 130 ml/min
Inlet O2 flow 35 ml/min
Main pyro O2 flow 450 ml/min
Furnace temp 1050 °C
Syringe volume 25 μl
Sample size 15 μl
Injection speed 1 μL/s
PMT voltage 700 V

Figure 1. S Calibration for the 0 – 25ppm range

The limit of detection or 3σ was determined using the calibration data. For this application range the data resulted in a LOD of 120ppb sulfur.


Figure 2 shows a selected representation of the injection signal distribution. In an attempt to cover the complete concentration range of the samples analysed, samples were selected. Results obtained for the last eleven ASTM ILS RFG reports are tabulated in Table 2.

A correlation between MultiTek results and the reported ILS robust mean for all the samples are plotted in Figure 3.

Figure 2. Sulfur results for 4 RFG samples (10 injections each)

Figure 3. D5453 correlation curve

Table 2. Comparison of ASTM ILS and Multitek® results

Sample ID ASTM RFG ILS S Different Mean (mg/Kg) Robust ILS SD # Labs MultiTek® S (mg/kg) 10 injections MultiTek®SD
RFG1006 4.8 0.64 93 4.8 0.06
RFG1008 4.9 0.54 94 5.0 0.08
RFG1009 4.7 0.73 96 4.0 0.03
RFG1010 15.5 1.35 91 16.7 0.07
RFG1011 5.7 0.66 92 5.9 0.26
RFG1012 5.7 0.65 93 5.8 0.10
RFG1101 8.0 0.93 88 7.6 0.31
RFG1102 8.3 0.93 92 8.9 0.34
RFG1103 10.6 1.17 95 10.6 0.10
RFG1104 1.9 0.46 87 1.8 0.04
RFG1105 4.3 0.68 95 4.3 0.12


The MultiTek analyzer is a highly stable and consistent instrument. Figure 4 shows the stability test on the MultiTek system: a 10 ppm sulfur sample exhibits excellent stability to ensure product quality and process monitoring.

Figure 4. Long term repeatability test on 10 ppm S sample


The results obtained show that the MultiTek analyzer is a powerful tool for determining sulfur content in order to ensure the final product quality of petrol based on the exceptional calibration linearity, low limit of detection, excellent repeatability and extremely stable response.

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About PAC L.P.

PAC is a leading global provider of advanced analytical instruments for laboratories and online process applications in industries such as refinery, petrochemical, biofuels, environmental, food & beverage, and pharmaceutical.

To provide its customers with cutting edge technology, PAC leverages significant R&D resources to support its core technologies, including chromatography, elemental analysis, physical properties, and software applications.

This information has been sourced, reviewed and adapted from materials provided by PAC L.P.

For more information on this source, please visit PAC L.P.

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